Di-μ-chlorido-bis[dichlorido(N,N-diethylacetamidinato)(N,N-diethylacetamidine)titanium(IV)] acetonitrile disolvate
نویسندگان
چکیده
In the centrosymmetric title compound [Ti(2)Cl(6)(C(6)H(13)N(2))(2)(C(6)H(14)N(2))(2)]·2C(2)H(3)N, an inversion center relates the two Ti atoms which display a distorted octa-hedral coordination geometry. There are two uncoordinated acetonitrile solvent mol-ecules per mol-ecule of title compound in the crystal structure.
منابع مشابه
Di-μ-oxido-bis[(1,4,8,11-tetraazacyclotetradecane-κ4 N,N′,N′′,N′′′)dimanganese(III,IV)] bis(tetraphenylborate) chloride acetonitrile disolvate
The title compound, [Mn(2)O(2)(C(10)H(24)N(4))(2)](C(24)H(20)B)(2)Cl·2CH(3)CN, is a mixed-valent Mn(III)/Mn(IV) oxide-bridged mangan-ese dimer with one chloride and two tetra-phenyl-borate counter-anions. There are two non-coordinated mol-ecules of acetonitrile in the formula unit. A center of inversion is present between the two metal atoms, and, consequently, there is no distinction between M...
متن کاملDi-μ-chlorido-chlorido-1κCl-(μ-1-phenyl-3-phenyliminobut-1-enolato-1:2κ3 O:O,N)bis(1-phenyl-3-phenyliminobut-1-enolato)-1κ2 N,O;2κ2 N,O-dichromium(III) toluene disolvate
In the title dichromium complex, [Cr(2)(C(16)H(14)NO)(3)Cl(3)]·2C(7)H(8), each Cr(III) atom has a distorted octa-hedral coordination geometry. The complex mol-ecule has three six-membered chelate rings formed by hydroxy-butane-imine ligands and the two Cr(III) atoms are bridged by two Cl atoms and one O atom.
متن کاملBis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate
In the centrosymmetric dinuclear title compound, [Ag(2)(C(36)H(26)N(8))(2)](PF(6))(2)·2C(2)H(3)N, the Ag(+) ion is bound to four N atoms from two 1,2-diphenyl-N,N'-bis-(di-2-pyridyl-methyl-eneamino)ethane-1,2-diimine ligands in a distorted tetra-hedral geometry. The ligand adopts a twist conformation, coordinating two metal centers by three pyridyl N atoms and one imine N atom and spanning two ...
متن کاملSynthesis, Crystal Structure and Antibacterial Evaluation of Di-μ-chlorido-bis({2-[(4-methoxyphenyl)- iminomethyl]pyridine-κ2N,N']Mercury(II)
New coordination polymer of [HgLCl2]n (1) with HgCl2 and Schiff base bidentate ligand (4-methoxyphenyl) pyridine-2yl methyleneamine (L) was prepared and structurally characterized. In the 1D network structure of 1, the mecury (II) ion adopts an HgN2Cl3 distorted square pyramid geometry. In this complex, one of the chlorine acts as bridging ligand connecting two adjacent mercury(II) ions while, ...
متن کاملBis[2-phenyl-1-(phenyliminio)isoindoline] di-μ-chlorido-bis[dichloridopalladate(II)] benzene disolvate
In the title compound, (C(20)H(17)N(2))(2)[Pd(2)Cl(6)]·2C(6)H(6), the dichloride-bridged [Pd(2)Cl(6)](2-) anion lies across an inversion center with each Pd(II) ion in a slightly distorted square-planar environment. In the crystal structure, two cations and an anion are connected via N-H⋯Cl hydrogen bonds between the NH groups of the iminioisoindoline cations and terminal Cl atoms of a hexa-chl...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007